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Maharashtra Board Class 12 Chemistry (S) Question Paper 2026 with Solution Pdf (Available Soon)

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Nidhi Bamnawat

| Updated On - Feb 20, 2026

The Maharashtra Board 2026 Class 12 Chemistry (S) Question Paper with Solution PDF is available here for download. The Chemistry (S) exam is scheduled to be held on 18th February, 2026 in the Morning Session from 11:00 AM to 2:00 PM.
The Maharashtra Board Class 12 Chemistry (S) exam 2026 was be a 70 mark written, offline paper comprising approximately 25% objective and 75% descriptive (short, long, essay-type).

Maharashtra Board Class 12 Chemistry (S) Question Paper 2026 with Solution PDF

Maharashtra Board Class 12 Chemistry (S) Question Paper 2026 Download PDF Check Solutions
Maharashtra Board Class 12 Chemistry Question Paper 2026 with Solution Pdf

Question 1(i):

The electrolyte used in \(H_2 - O_2\) fuel cell is ______.

  • (A) aqueous \(KCl\)
  • (B) aqueous \(KOH\)
  • (C) aqueous \(HCl\)
  • (D) aqueous \(KNO_3\)

Question 1(ii):

The oxidation state of bromine in \(HOBrO_2\) oxoacid is ______.

  • (A) \(+7\)
  • (B) \(+5\)
  • (C) \(+3\)
  • (D) \(+1\)

Question 1(iii):

Acetonitrile may be prepared by heating the following reactants:

  • (A) Ethyl chloride with alcoholic \(KCN\)
  • (B) Ethyl chloride with alcoholic \(AgCN\)
  • (C) Methyl chloride with alcoholic \(KCN\)
  • (D) Methyl chloride with alcoholic \(AgCN\)

Question 1(iv):

The carbonated water is an example of ______.

  • (A) solid in liquid solution
  • (B) liquid in liquid solution
  • (C) gas in liquid solution
  • (D) liquid in gas solution

Question 1(v):

The unit of rate constant is per second, the order of reaction is \textendash

  • (A) Zero
  • (B) First
  • (C) Second
    (D) Third

Question 1(vi):

A system releases \(10 kJ\) of heat and performs \(15 kJ\) of work on the surrounding. Hence the change in internal energy is :

  • (A) \(+ 5 kJ\)
  • (B) \(- 5 kJ\)
  • (C) \(+ 25 kJ\)
  • (D) \(- 25 kJ\)

Question 1(vii):

The co-ordination complex ions \([Co(NH_3)_5(NO_2)]^{2+}\) and \([Co(NH_3)_5(ONO)]^{2+}\) are ______ of each other.

  • (A) ionization isomers
  • (B) solvate isomers
  • (C) linkage isomers
  • (D) co-ordination isomers

Question 1(viii):

The correct order for basic strength of amines and ammonia is ______.

  • (A) \(NH_3 > R-NH_2 > R_2NH > R_3N\)
  • (B) \(NH_3 > R_3N > R_2NH > R-NH_2\)
  • (C) \(NH_3 < R-NH_2 > R_3N > R_2NH\)
  • (D) \(NH_3 < R-NH_2 < R_2NH > R_3N\)

Question 1(ix):

Amongst the following \(3d\)-series elements, having highest value of first ionization enthalpy is ______.

  • (A) \(Zn\)
  • (B) \(Cu\)
  • (C) \(Co\)
  • (D) \(Sc\)

Question 1(x):

The \(pOH\) of \(0.01 M HCl\) solution is ______.

  • (A) \(1\)
  • (B) \(2\)
  • (C) \(11\)
  • (D) \(12\)

Question 2(i):

Write the name of product obtained, when selenium is treated with magnesium metal.


Question 2(ii):

Write the SI unit of cell constant.


Question 2(iii):

Write the name of radioactive element in lanthanide series.


Question 2(iv):

Complete the following reaction :


Question 2(v):

Write the IUPAC name of :



Question 2(vi):

Copper has fcc structure with edge length \(495 pm\). What is the radius of copper atom in pm?


Question 2(vii):

Write the chemical name of Teflon.


Question 2(viii):

Write the name of nanoparticle which acts as highly effective bacterial disinfectant.


Question 3(a):

Define Isomorphism.


Question 3(b):

Define Unit Cell.


Question 4(i):

Explain the trends in atomic radii of group 17 elements.


Question 4(ii):

Explain the trends in electronegativity of group 17 elements.


Question 5:

Explain Homoleptic and Heteroleptic complexes with example.


Question 6(a):

Write the reaction of bromine water on glucose.


Question 6(b):

Define Enantiomers


Question 7(i):

Write example of one dimensional nanostructure of size less than \(100 nm\).


Question 7(ii):

Write the hydrolysis reaction of ethyl methyl ether.


Question 8:

Calculate the osmotic pressure of solution containing \(0.822 gm\) of sucrose in \(300 mL\) of water at \(298 K\). [Given : Molar mass of sucrose \(342 g/mol\), \(R = 0.08205 dm^3 atm. K^{-1} mol^{-1}\)]


Question 9(a):

Write the mathematical equation of first law of thermodynamics for following processes : Isochoric process


Question 9(b):

Write the mathematical equation of first law of thermodynamics for following processes : Adiabatic process


Question 10:

Write two similarities and two differences between lanthanoids and actinoids.


Question 11(i):

What is the action of conc. \(HNO_3\) on chlorobenzene?


Question 11(ii):

What is the action of fuming \(H_2SO_4\) on chlorobenzene?


Question 12:

Explain Cannizzaro reaction with suitable example.


Question 13:

A chemical reaction occurs in two steps :

(i) \(NO_2Cl(g) \xrightarrow{slow} NO_2(g) + Cl(g)\)

(ii) \(NO_2Cl(g) + Cl(g) \xrightarrow{fast} NO_2(g) + Cl_2(g)\)

(a) Write down the rate law.

(b) Identify the reaction intermediate.


Question 14:

The standard potential of electrode \(Cu^{2+}(0.02 M) | Cu(s)\) is \(0.337 volt\). Calculate its potential in volt.


Question 15(i):

Derive relationship between relative lowering of vapour pressure and molar mass of non volatile solute.


Question 15(ii):

Write statement of second law of thermodynamics.


Question 16(i):

Convert acetamide into ethyl amine.


Question 16(ii):

Explain amphoteric nature of water.


Question 17(i):

Convert Ethanol into sodium ethoxide.


Question 17(ii):

Convert Phenol into o-phenol sulfonic acid.


Question 17(iii):

Convert Bromomethane into methoxyethane.


Question 18(i):

What is peptide linkage?


Question 18(ii):

Write general characteristics of interhalogen compounds.


Question 19(i):

Write observed electronic configuration of chromium (\(Z = 24\)).


Question 19(ii):

Calculate magnetic moment of \(Ti^{3+}\) by using spin only formula. (\(Z\) of \(Ti = 22\))


Question 19(iii):

Define Green chemistry.


Question 20(i):

Write examples of coordination metal complexes in biology.


Question 20(ii):

Calculate the work done in oxidation of 2 moles of \(SO_2\) at \(298 K\), if \(SO_{2(g)} + \frac{1}{2}O_{2(g)} \rightarrow SO_{3(g)}\). [Given : \(R = 8.314 J/K mol\)]


Question 21(i):

Write the formula to measure % atom economy according to green chemistry.


Question 21(i)(a):

Convert Benzene into benzaldehyde.


Question 21(ii)(b):

Convert Cyclohexene into adipic acid.


Question 22(i):

Write a reaction for preparation of Nylon-6.


Question 22(ii):

The salt of \(Sc^{3+}\) ion is colourless and the salt of \(Mn^{3+}\) ion is coloured. Explain. [\(Z\) of \(Sc = 21\) and \(Z\) of \(Mn = 25\)]


Question 23(i):

Write the postulates of Werner's theory of co-ordination complexes.


Question 23(ii):

What is the action of ethane-1,2-diol on acetone?


Question 24(i):

Write Tollen's reagent test for acetaldehyde.


Question 24(ii):

Write the structure of zwitter ion of sulfanilic acid.


Question 24(iii):

Write the reaction between benzene diazonium chloride and phenol in alkaline medium.


Question 25(i):

Define Common ion effect.


Question 25(ii):

Write preparation of glucose from starch.


Question 26(i):

Draw the structure of 2, 4 \textendash\ dinitrophenylhydrazone of acetaldehyde.


Question 26(ii):

The rate of \(A + B \rightarrow P\) is \(3.6 \times 10^{-2} mol/dm^3/s\). When \([A] = 0.2 M\) and \([B] = 0.1 M\). Calculate the rate constant if reaction is first order in \(B\) and second order in \(A\).


Question 27(i)(a):

Define Isotonic solution.


Question 27(i)(b):

Define Molecularity of reaction.


Question 27(ii):

State and explain Hess's law of constant heat summation.


Question 28(i)(a):

Define Schottky defect.


Question 28(i)(b):

Define Ferromagnetism.


Question 28(ii):

Write the name of catalyst used in preparation of HDP.


Question 28(iii):

Draw structure of isoprene unit of natural rubber.


Question 29(i):

Calculate effective atomic number of \(Fe^{2+}\) in \([Fe(CN)_6]^{4-}\). [Given : (\(Z = 26\))]


Question 29(ii):

Draw neat and labelled diagram of lead accumulator.


Question 29(iii):

Write two advantages of hydrogen \textendash\ oxygen fuel cell.


Question 30(i):

Convert ethanoic acid into ethanol.


Question 30(ii):

Explain the mechanism of alkaline hydrolysis of bromomethane.


Question 31(i):

Acetic acid is 5% ionised in its decimolar solution. Calculate the dissociation constant of acetic acid.


Question 31(ii):

Write chemical formula of epsom salt. Give two uses of \(H_2SO_4\).

*The article might have information for the previous academic years, please refer the official website of the exam.

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